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102191-92-4
Acetaldehyde, 2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-

Catalog#:1P0007BC

CAS:102191-92-4

MDL:MFCD01321229

Molecular Formula:C8H18O2Si

Molecular Weight:174.3128

UN Number:

Haz Class:

Packing Group:

Synonyms: 102191-92-4; (tert-Butyldimethylsilyloxy)acetaldehyde; 2-[(tert-butyldimethylsilyl)oxy]acetaldehyde; Acetaldehyde, [[(1,1-dimethylethyl)dimethylsilyl]oxy]-; (tert-Butyldimethylsiloxy)acetaldehyde, 90%; PubChem20197; ACMC-1BT5X; SCHEMBL64584; AC1N514K; DTXSID40400520; MEBFFOKESLAUSJ-UHFFFAOYSA-N; (tert-Butyldimethylsilyloxy)ethanal; 2-((tert-Butyldimethylsilyl)oxy)acetaldehyde; t-butyldimethylsilyloxylacetaldehyde; tert-butyldimethylsiloxyacetaldehyde; t-butyldimethylsilyloxy acetaldehyde; (t-butyldimethylsilyloxy)acetaldehyde; tert-butyldimethylsilyloxyacetaldehyde; ANW-63549; BBL103211; MFCD01321229; STL557021; t-butyldimethylsilanyloxy acetaldehyde; 2-(tert-butyldimethylsilyloxy)acetaldehyde; (t-butyldimethylsilyloxy) acetaldehyde; tert-butyldimethylsilyloxy acetaldehyde; tert-butyldimethylsilyloxy-acetaldehyde; 2-(tert-butyldimethylsilyloxy)-ethanal; AKOS016003622; ZINC169743407; RL00110; TRA0020272; (tertbutyldimethylsilanyloxy)acetaldehyde; (tert-butyldimethylsilyl-oxy)acetaldehyde; (tert-butyldimethylsiloxy)acetaldehyde; (tert-butyldimethylsilyloxy) acetaldehyde; (tert-butyldimethylsilyloxy)-acetaldehyde; (tert-Butyldimethylsilanyloxy)acetaldehyde; 2-tert-butyl-dimethylsilyloxy-acetaldehyde; AK-80199; BC231075; SC-53510; (tert-butyl-dimethylsilanyloxy)acetaldehyde; (tert-butyl-dimethylsilanyloxy)-acetaldehyde; 2-(tert-butyldimethylsilyloxy) acetaldehyde; t-butyldimethylsiloxyacetaldehyde; 2-(tert-butyldimethylsilyloxy)-acetaldehyde; DB-008736; RT-024217; (tert-butyl-dimethyl-silanyloxy)-acetaldehyde; 2-(tert-butyl-dimethylsilanyloxy)acetaldehyd; 2-(tert-butyl-dimethylsilanyloxy)acetaldehyde; FT-0694254; (tert-Butyldimethylsilyloxy)acetaldehyde, 90%; 2-[tert-butyl (dimethyl)silyl]oxyacetaldehyde; KS-00001954; 2-[tert-butyl(dimethyl)silyl]oxyacetaldehyde; {[(tert-butyl)(dimethyl)silyl]oxy}acetaldehyde; 120145-EP2295426A1; 120145-EP2298778A1; 191B924; [[(1,1-dimethylethyl)dimethylsilyl]oxy]acetaldehyde; J-506623; J-640403; J-800376; [[(1,1-dimethylethyl)-dimethylsilyl]-oxy]acetaldehyde; [[(1,1-dimethylethyl)dimethylsilyl]oxy]-acetaldehyde; t-butyldimethylsilyloxyacetaldehyde; {[(1,1-dimethylethyl)(dimethyl)silyl]oxy}acetaldehyde; 2-[(1,1-dimethylethyl)dimethylsilyloxy]-acetaldehyde; Acetaldehyde, 2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-; 1R-Camphanic acid; 2-(2-Bromoethyl)oxirane; CID4187788; 2-(dimethyl-tert-butyl-silyl)oxyacetaldehyde; tert-Butyldimethylsilyloxy)acetaldehyde; {[tert-butyl(dimethyl)silyl]oxy}acetaldehyde;

Keywords: 102191-92-4,MFCD01321229,1P0007BC,Acetaldehyde, 2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-,C8H18O2Si

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  • Acetaldehyde, 2-[[(1,1-dimethylethyl)dimethylsilyl]oxy]-, often referred to as a silyl ether acetaldehyde derivative, is a specialized chemical used mainly in organic synthesis as a protective group and a synthetic intermediate.
    
    In organic chemistry, the protection of alcohols, aldehydes, and ketones is of paramount importance to control the reactivity of these functional groups and steer the course of chemical reactions. The use of silyl ether derivatives, like the one mentioned, serves as a protective group for the aldehyde functionality. By temporarily modifying the aldehyde, chemists can prevent it from engaging in unwanted side reactions or being affected by conditions that might otherwise degrade it.
    
    Once the desired reactions on other parts of the molecule are complete, the silyl protective group can be selectively removed, typically under mild acidic or basic conditions, to liberate the free aldehyde. This strategy is quite useful in multistep synthesis procedures where the selective reactivity must be tightly controlled.
    
    Furthermore, such silyl-protected aldehyde can act as synthetic intermediates. They can be involved in various chemical transformations including C-C bond-forming reactions like Aldol condensation or as a starting material for the synthesis of complex natural products and pharmaceuticals. The protection strategy allows for easier purification processes, as the silyl group often improves the volatility or solubility properties of the intermediate, enabling techniques like chromatography to be more effective.
    
    By applying such a compound, chemists can manipulate reaction pathways, protect sensitive functional groups until a later stage in the synthesis, and ultimately achieve higher yields and cleaner reactions for the creation of a wide array of chemical products.

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