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787618-22-8
2-Dicyclohexylphosphino-2,6-DI-I-Propoxy-1,1-Biphenyl

Catalog#:1P0033QW

CAS:787618-22-8

MDL:MFCD06798294

Molecular Formula:C30H43O2P

Molecular Weight:466.6350

UN Number:

Haz Class:

Packing Group:

Synonyms: 787618-22-8; Ruphos; PHOSPHINE, [2',6'-BIS(1-METHYLETHOXY)[1,1'-BIPHENYL]-2-YL]DICYCLOHEXYL-; 2-Dicyclohexylphosphino-2,6-diisopropoxy-1,1-biphenyl; 2-Dicyclohexylphosphino-2,6-DI-I-Propoxy-1,1-Biphenyl; dicyclohexyl-[2-(2,6-diisopropoxyphenyl)phenyl]phosphane; AK-86040; Y-200008; Phosphine, (2',6'-bis(1-methylethoxy)(1,1'-biphenyl)-2-yl)dicyclohexyl-; Dicyclohexyl(2',6'-diisopropoxy-[1,1'-biphenyl]-2-yl)phosphine;2-Dicyclohexylphosphino-2',6'-diisopropoxy-1,1'-biphenyl; Ruphos phosphine ligand [MI]; RuPhos, 95%; Dicyclohexyl(2',6'-diisopropoxy-[1,1'-biphenyl]-2-yl)phosphine; SCHEMBL16771; Buchwald phosphine ligands, ruphos phosphine ligand-; C30H43O2P; CTK8B4848; DTXSID10584700; MXFYYFVVIIWKFE-UHFFFAOYSA-N; BCP21883; ANW-46517; BBL103800; MFCD06798294; 2-DICYCLOHEXYLPHOSPHINO-2',6'-DIISOPROPOXY-1,1'-BIPHENYL; RW2258; STL557610; ZINC12359448; AKOS015840829; CS-W007432; GC10134; RL05043; RTR-025151; KS-0000026C; AC-28790; 2-Dicyclohexylphosphino-2',6'-diisopropoxybiphenyl; AJ-61512; AN-27399; AS-18551; SY009817; AB0007483; AX8074362; ST2412797; TR-025151; D5037; FT-0689981; 2-DICYCLOHEXYLPHOSPHINO-2',6'-DI-I-PROPOXY-1,1'-BIPHENYL; W8468; MFCD06798294 (95%); 2-Dicyclohexylphosphino-2,6-diisopropoxybiphenyl; 618D228; 2,6-Diisopropoxy-2'-(dicyclohexylphosphino)biphenyl; 2-dicyclohexylphosphino-2',6'-diisopropoxy biphenyl; J-509271; I14-10046; 2-dicyclohexylphosphino-2',6'-di-i-propoxy-1,1-biphenyl; dicyclohexyl-(2',6'-diisopropoxy-biphenyl-2-yl)-phosphane; UNII-X3474RY19E; 2-dicyclohexylphosphino-2',6'-di-iso-propoxy-1,1'-biphenyl; [2',6'-bis(propan-2-yloxy)biphenyl-2-yl](dicyclohexyl)phosphane; dicyclohexyl(2',6'-diisopropoxy-[1,1'-biphenyl]-2-yl)phosphane; {2',6'-bis[(1-methylethyl)oxy]-2-biphenylyl}(dicyclohexyl)phosphane; {2',6'-Bis[(propan-2-yl)oxy][1,1'-biphenyl]-2-yl}(dicyclohexyl)phosphane; 2-Dicyclohexylphosphino-2 inverted exclamation mark ,6 inverted exclamation mark -diisopropoxybiphenyl; 2-Dicyclohexylphosphino-2 inverted exclamation marka,6 inverted exclamation marka-diisopropoxybiphenyl; ACN-001331; (2r,3r)-(+)-bis(diphenylphosphino)butane; 2-(Dicyclohexylphosphino)-2/',6/'-isopropoxybiphenyl; DICYCLOHEXYL(2',6'-DIISOPROPOXYBIPHENYL-2-YL)PHOSPHINE; [2',6'-bis(propan-2-yloxy)-[1,1'-biphenyl]-3-yl]dicyclohexylphosphane; 74839-84-2; X3474RY19E; 2-(Dicyclohexylphosphino)-2',6'-isopropoxybiphenyl;

Keywords: 787618-22-8,MFCD06798294,1P0033QW,2-Dicyclohexylphosphino-2,6-DI-I-Propoxy-1,1-Biphenyl,C30H43O2P

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Catalog# Purity Size Price Dis. Price Availability Quantity
1P0033QW 97% 250mg $6.00 $4.00 In Stock USA ADD TO CART BUY NOW
1P0033QW 97% 1g $11.00 $9.00 In Stock USA ADD TO CART BUY NOW
1P0033QW 97% 5g $14.00 $11.00 In Stock USA ADD TO CART BUY NOW
1P0033QW 97% 10g $17.00 $13.00 In Stock USA ADD TO CART BUY NOW
1P0033QW 97% 25g $39.00 $29.00 In Stock USA ADD TO CART BUY NOW
1P0033QW 97% 100g $153.00 $115.00 In Stock USA ADD TO CART BUY NOW

  • 2-Dicyclohexylphosphino-2',6'-di-i-propoxy-1,1'-biphenyl, often abbreviated as DtBPF, is an organophosphorus compound used primarily as a ligand in coordination chemistry and homogeneous catalysis. Its structure features a biphenyl backbone substituted with both dicyclohexylphosphino and diisopropoxy groups, which allows it to bind to transition metals and create complex catalyst systems.
    
    This compound has a stereochemically demanding structure, which can create chiral environments when coordinated to metals, thus making it particularly useful in asymmetric catalysis. It has found utility in a variety of complex synthetic processes, including:
    
    1. **Hydrogenation Reactions**: The ligand can coordinate to a variety of metals to create catalysts suitable for asymmetric hydrogenation of unsaturated substrates, such as alkenes, aldehydes, and ketones, to give chiral, non-racemic products.
    
    2. **C-C Bond Formation**: It can be used in cross-coupling reactions, such as Suzuki, Stille, Heck, and Negishi reactions, where the ligand's ability to stabilize the metal catalyst enhances the reaction's selectivity and efficiency.
    
    3. **Oxidation and Reduction Reactions**: When coordinated to appropriate metal complexes, the ligand can facilitate oxidation and reduction reactions involving a wide range of functional groups.
    
    4. **Activation of Small Molecules**: The ligand can stabilize metal complexes that are capable of activating small molecules like carbon dioxide, nitric oxide, and nitrogen, thus enabling their incorporation into organic molecules.
    
    5. **Homogeneous Catalyst Recycling**: The steric bulk of DtBPF allows for easy separation of the catalyst-ligand complexes from the reaction mixture, often enabling catalyst recycling, which is an important consideration for industrial applications and green chemistry.
    
    The particular arrangement of substituents on the ligand can greatly influence the steric and electronic properties of the metal center it binds to, which in turn would affect the activity, selectivity, and stability of the catalyst. In synthetic chemistry, the careful design of ligands like DtBPF allows chemists to tailor catalysts for specific reactions, enhancing the efficiency and selectivity of synthetic processes, and making it an indispensable tool in the synthesis of complex organic molecules.

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